The circuit pictured here does just that. The mains 220Volt voltage is led through two 30k resistors to a bridge rectifier that gives a double phased rectified signal to a 4N25 opto coupler. The LED in this opto coupler thus goes low with a frequency of 100Hz and the signal on the collector is going high with a frequency of 100Hz, in line with the sinusoid wave on the mains net.
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